Experimental and numerical investigations on the heat production and thermal storage characteristics of rapid preparation amorphous powder activated coke

The heat production and thermal storage characteristics of rapid-preparation amorphous powder activated coke (RAC) were investigated. RAC was prepared by using a drop-tube reactor system. The natural oxidation characteristics of RAC were studied through combined TG–FTIR analysis and temperature-programmed experiment. Experimental results showed that CO and CO₂ were the main oxidation products of RAC in air, and that the oxidation reaction was in accordance with the Arrhenius equation and law of mass action. Thermal storage characteristics were studied through computational fluid dynamics simulation. The maximum excess temperature θ_max increases linearly with the increase of the initial temperature. The concentration fields of the products show that CO₂ is mainly concentrated in the upper part of the coke bin, and the CO generated by CO₂ at high temperature is mainly concentrated in the central part of the coke bin.     

Effects of non-thermal plasma treating wheat kernel on the physicochemical properties of wheat flour and the quality of fresh wet noodles

The effects of non-thermal plasma (NTP) on the physicochemical properties of wheat flour and the quality of fresh wet noodles ( FWN) were investigated. The results showed that NTP effectively decreased the total plate count (TPC), yeast and mould count (YMC) and Bacillus spp. in wheat flour. Wet gluten contents and the stability time reached the maximum when treated for 20 s. The viscosity of starch increased significantly after treatment due to the increased of damaged starch. The contents of secondary structure were altered to some extent, which was because that the ordered network structure of gluten protein broken. Furthermore, compared with the control, texture properties of FWN were enhanced significantly at 20 s, and the darkening rate of FWN was greatly inhibited due to the low polyphenol oxidase (PPO) activity. Consequently, the most suitable treatment was 500 W for 20 s, providing a basis for the application of NTP in flour products.     

超高分子量聚乙烯纤维增强中空蜂窝模压复合材料性能研究

为研制车船等壳体所用的轻质、高强复合板材,选用超高分子量聚乙烯(UHMWPE)短纤维纱,制备成单层经纬为120根/(10 cm)的平纹组织,采用多组经纱持续更替交织层的方法制成2L(1+0)型、4L(2+1)型、6L(3+2)型3种多层角联锁结构织物,采用扦插芯棒、模压成型方法制成菱形蜂窝状的热固性环氧树脂基中空板,并与2块真空吸液法制成的面板组成“三合一”复合板,同时测定了复合板材的结构特征及其平拉、平压和弯曲性能。结果表明:3种类型复合板的密度均远小于水的密度,其中6L(3+2)型最小,为0.48 g/cm³;复合板层数越多,环氧树脂越难渗透尤其是在中空板菱形交叉点处,复合板平拉、平压、抗弯曲强度则呈现递增,制成的6L(3+2)型复合板试样平压强度可达到1.03 MPa。     

日本の寒地，北海道における2030年代の水稲生育への温暖化の影響予測とその対応(日语原文)

北海道では1980年代から2010年代まで，水稲圃場栽培期間である5–9月の気温は年代とともに上昇した。そこで，直近の2010年代（2010—2019年平均）と比べて， 2つの2030年代の予測気象から，既報の関係式より水稲生育を予測した。その結果，2030年代では2010年代に比べ，限界移植日（移植早限）が水稲栽培17地域の平均で8～9日早い。また，早限出穂期が1～5日早く，晩限出穂期が1～5日遅く，安全出穂期間が2～10日長い。出穂期は1～3日早い。出穂期から晩限出穂まで2～9日長いため，遅延型冷害の発生がやや少ない。生育期別気象は，出穂前24日以降30日間では生育が早いため平均気温が同じかやや低い。出穂前10日以降40日間および出穂期以降40日間では平均気温がやや高く，日射量はやや少ない。そのため，玄米収量は96～98％とやや低く，潜在収量性を示す気候登熟量示数は同じである。障害不稔発生に関係する穂ばらみ期冷害危険期の平均気温はわずかに低いかほぼ同じであるため，冷害発生の危険性は残る。一方，不稔発生をもたらす低温域の出現頻度には，地域間で差異がある。精米蛋白質含有率は同じであるが，アミロース含有率はやや低く，やや良食味である。米粒外観品質では被害粒歩合と着色粒歩合は一定の傾向がなく，未熟粒歩合はやや高い。精米白度は同じであるが，玄米白度はやや高い。以上の予測に対する技術的対応方向を示した。     

Comparative study of EICP treatment methods on the mechanical properties of sandy soil

This study analyzed the effect of different treatment methods in enzyme-induced carbonate precipitation (EICP) on the mechanical properties of soil. Soybean crude urease was used to catalyze the precipitation of calcium carbonate (CaCO₃). A multiple-phase method was proposed and further compared with commonly practiced EICP treatment methods (including the one-phase method, two-phase method, and premix-and-compact method) from the aspects of chemical conversion efficiency, CaCO₃ precipitation distribution, permeability, and unconfined compressive strength. Based on the findings, the characteristics of each method were further discussed and summarized. Although the enzymatic CaCO₃ precipitation generated from all the treatment methods could potentiate the soil strength to a great or less degree, using the proposed multiple-phase method could bring about a high chemical conversion efficiency, uniform distribution of CaCO₃ as well as preferable permeability retention. In addition, the multiple-phase method could significantly improve the efficiency of urease usage.     

Influence of thermal runaway in styrene–acrylonitrile bulk copolymerization revealed by computational fluid dynamics modeling

The computational fluid dynamics (CFD) and kinetic-based moment methods coupled approach is adopted to simulate the bulk copolymerization of styrene–acrylonitrile (SAN) in a stirred tank reactor. Numerical simulations are carried out to investigate the impacts of impeller speed, monomer ratio, initiator ratio, and initial reaction temperature on the copolymerization process and product properties. Particularly, the Chaos theory is selected as a criterion for evaluating the occurrence of the thermal runaway. The Flory's and Stockmayer's distributions are employed to calculate chain length distribution and copolymer composition distribution of copolymer. The simulation results highlight that the appearance of thermal runaway can be postponed by properly increasing the rotation speed, decreasing the initiator loadings, initial acrylonitrile contents and initial reactor temperature. Furthermore, significant differences exist in the product properties that predicted by the ideal and non-ideal models, which demonstrates that the temperature heterogeneity plays a crucial role in SAN copolymerization. This study could offer references for the safe operation and design of polymerization processes.     

Improved thermal stability of the near-infrared Al-modulated Zn3Ga2GeO8: Cr3+ phosphors for plant growth applications

The exploration of the high thermal stability near-infrared (NIR) phosphors is significantly crucial for the development of plant lighting. However, NIR phosphors suffer from the poor chemical and thermal stability, which severely limits their long-term operation. Here, the successful improvement of luminous intensity (149.5%) and thermal stability at 423 K of Zn₃Ga₂GeO₈ (ZGGO): Cr³⁺ phosphors is achieved for the introduction of Al³⁺ ions into the host. The release of carriers in deep traps inhibits the emission loss for the thermal disturbance. Furthermore, an NIR light emitting diodes (LEDs) lamp is explored by combining the optimized Zn₃Ga_1.1675Al_0.8GeO₈: 0.0325Cr³⁺ phosphors with a commercial 460 nm blue chip, and the emission band can match well with the absorption bands of photosynthetic pigments and the phytochrome (P_R and P_FR) of plants. The explored LEDs lamp further determines the growth and the pheromone content of the involved plants for the participation of the NIR emission originated from Cr³⁺ ions. Our work provides a promising NIR lamp as plant light with improved thermal stability for long-term operation.     

Preparation of high-purity SiC ceramics with good plasma corrosion resistance by hot-pressing sintering

High-purity SiC ceramic devices are applied in semiconductor industry owing to their outstanding properties. Nevertheless, it is difficult to densify SiC ceramics without any sintering additive even by HP sintering. In this work, high-purity and dense SiC ceramics were fabricated by HP sintering with very low amounts of sintering aids. Residual B content was only 556 ppm and relative density was more than 99.5%. Furthermore, thermal conductivity of as-prepared SiC ceramics was improved from 155 W m^?1 K^?1 to 167 W m^?1 K^?1 by increasing holding time and their plasma corrosion resistance was promoted in the meantime. The as-prepared high-purity SiC ceramics have broad application prospects in the field of semiconductor industry.     

配分工艺对中碳Ti-Mo高强Q&P钢组织和性能的影响

摘要：采用盐浴实验、扫描电镜、透射电镜、拉伸实验和磨损实验等手段，研究了配分工艺对中碳Ti Mo钢组织和性能的影响，分析了不同配分工艺处理下的组织演变和性能变化。结果表明，显微组织主要由回火马氏体、渗碳体、(Ti，Mo)C粒子组成。随着配分时间的延长和配分温度的升高，板条马氏体数量减少，马氏体板条厚度增加，边界钝化。此外，随着配分温度从310℃提高至400℃，抗拉强度、硬度和低温冲击韧性同时下降，分别降低约250MPa、56HV和15J。最后，Ms以下温度配分（310℃）试样的耐磨损性能明显优于Ms以上温度配分（400℃）试样。Ms以下温度配分试样磨损表面形貌以塑性变形为主，Ms以上温度配分试样磨损表面以犁沟为主。     

Centrifugally spun carbon fibers prepared from aqueous poly(vinylpyrrolidone) solutions as binder-free anodes in lithium-ion batteries

Aqueous solutions of poly(vinylpyrrolidone) (PVP) of various concentrations (20, 25, and 28 wt%) were successfully spun into fibers by centrifugal spinning. The pristine PVP fibers were annealed and carbonized to produce flexible carbon fibers for use as binder-free anodes in lithium-ion batteries. These flexible carbon fibers were prepared by developing a novel three-step heat treatment to reduce the residual stresses in the pristine PVP precursor fibers, and to prevent fiber degradation during carbonization. The thermogravimetric analysis data showed that the annealed fibers yielded a residual mass percentage of 36.0% while the pristine PVP fibers suffered a higher mass loss and only retained 26.5% of original mass above 450 °C (under nitrogen). The electrochemical performance of the carbon-fiber anodes was evaluated by conducting galvanostatic charge/discharge, rate performance, and cycle voltammetry experiments. The 20, 25, and 28 wt% derived binder-free anodes delivered specific charge capacities of 205, 189, and 275 mAh g⁻¹, respectively, after the first cycle at a current density of 100 mA g⁻¹. The results obtained in this work indicate that a feasible pathway towards a large-scale production of carbon-fiber anodes from a 100% aqueous solution can be achieved via centrifugal spinning and subsequent heat treatment.